چکیده
|
Molten salts and ionic liquids are both liquids mainly composed of ions. ILs and MSs are defined
as those fused salts with a melting point less than 100 °C, with salts with higher melting points
mentioned to as molten salts [1]. Also, the anomeric effect is a fundamental concept, which
includes an interaction between the lone pair electrons of heteroatom and the anti-bonding
orbitals of adjacent bonds and can control reaction mechanism. In this regard, a new term
"anomeric based oxidation" is introduced for unusual hydride releasing from crabon [2],
[3].Therefore we decided to design and synthesize a novel, task-specific MSs for synthesis of 2-
Amino-3,5-dicarbonitrile-6-sulfanylpyridine derivatives via Anomeric Based of Oxidation
mechanism.
|